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Ensinger PEI

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Nouryon Trigonox C Thermoset tert-Butyl peroxybenzoate
Categories: Other Engineering Material

Material Notes: Organic peroxide used for curing unsaturated polyester resins, vinylester and acrylic resin at elevated and high temperatures; preferred for curing UP resin based Hot Press Moulding formulations (SMC, BMC, DMC etc.) in the temperature range of 120-170°C.

CAS number: 614-45-9

EINECS/ELINCS No: 210 382-2

Applications: Polymerization of styrene: Trigonox C may be used for the (co)polymerization of styrene in the temperature range of 100- 140°C. In practice, combinations of two or more peroxides with diverging activities are used to reduce the residual monomer content in the final polymer and to increase reactor efficiency. Polymerization of ethylene: Trigonox C is an efficient initiator for the ethylene polymerization at high pressure in both autoclave and tubular processes. To obtain a wide spectrum of polymerization temperatures, Trigonox C is often used in combination with other peroxides. Depending on reaction conditions, Trigonox C is active in the temperature range of 220-270°C. Polymerization of acrylates and methacrylates: Trigonox C may be used as an initiator for the bulk, suspension and solution (co)polymerization of acrylates and methacrylates in the temperature range of 90-130°C. For Thermoset: Trigonox C, tert-butyl peroxybenzoate, is an aromatic perester, which is used for the curing of unsaturated polyester resins at elevated temperatures. Trigonox C is preferred for the curing of UP resin based Hot Press Moulding formulations (SMC, BMC etc.) in the temperature range of 120-170°C. Trigonox C can also be used in combination with high reactive peroxides like Perkadox 16 or Trigonox HMa as kicker in formulations for pultrusion in the temperature range of 100-150°C. In combination with a cobalt accelerator (e.g. Accelerator NL-53N, 10% cobalt), Trigonox C is also applicable for the cure of UP resins in the temperature range of 70°C and higher. Application area can be: air drying lacquers, diplacquers, filament winding, etc. For Crosslinking: Trigonox C is a monofunctional peroxide which is used for the crosslinking of natural rubber and synthetic rubbers, as well as polyolefins. Safe processing temperature: 100°C (rheometer ts2 > 20 min.). Typical crosslinking temperature: 140°C (rheometer t90 about 12 min.).

Information provided by Nouryon

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Physical PropertiesOriginal ValueComments
Density 1.04 g/cc
Half-life 0.100
@Temperature 142 °C
[hr]
 1.00
@Temperature 122 °C
[hr]
 10.0
@Temperature 103 °C
[hr]
Viscosity 6.5 cP
Molecular Weight 194.2 g/mol
Storage Temperature 10.0 - 25.0 °C
 
Thermal PropertiesOriginal ValueComments
Crystallization Temperature 8.00 °C
Decomposition Temperature 60.0 °CSelf-Accelerating Decomposition Temperature
 
Processing PropertiesOriginal ValueComments
Shelf Life 3.00 Month
 
Descriptive Properties
AppearanceClear liquid
Assay= 98.0 %
Color= 100 Pt-Co / APHA
Content= 0.10 %Hydroperoxides as TBHP
 = 50 mg/kgInorganic + organic hydrolysable chloride
 = 8.07 %Active oxygen
Content (%)8.24Active oxygen content peroxide

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PNOURY1171 / 286694

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