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Rulon Bearings

Celanese 50000437 Acetic Anhydride
Categories: Fluid

Material Notes: CAS Number: 108-24-7

Product description: Acetic Anhydride is a clear, colorless liquid with a very pungent, penetrating, vinegar-like odor. It is completely miscible with diethyl ether and can be easily dissolved in the usual organic solvents; it reacts with alcohols. Acetic Anhydride is an excellent solvent for numerous organic and inorganic products. In the presence of water, Acetic Anhydride reacts slowly at room temperature to form acetic acid. At moderate and elevated temperatures, however, this reaction can be extremely exothermic and violent. It is accelerated by catalytic quantities of sulfuric acid or other mineral acids and may even be explosive.

Possible Applications: In the chemical industry, the reactivity of the acetyl group of Acetic Anhydride is used to synthesize end products and intermediates. Acetic Anhydride is widely employed industrially for its acetylating and dehydrating properties. A major use for it is the acetylation of cellulose to produce acetate fibers, plastics, coatings and films. It is especially valuable for the direct esterification of alcohols where acetic acid cannot be used. Another large use for Acetic Anhydride is in the manufacture of acetylsalicylic acid (aspirin), acetylcholine hydrochloride, acetophenacetin, sulfonamides, aceto-p-aminophenol, cortisone, acetanilide, theophylline, sulfa drugs, certain vitamins and hormones; and many other pharmaceuticals and pharmaceutical intermediates. Acetic Anhydride is also used to produce acetyl ricinoleates, triacetin, acetyl tributyl citrate, and other plasticizers. Triacetic glycerol esters are used as plasticizers in the plastics and paint industry, as fixatives in perfumery and as solvents for fungicides and basic dyes. Acetylated fatty acid monoglycerides and acetylated animal and vegetable fats are used as additives and auxiliaries in the food industry. In this connection, the relevant statutory food regulations must be observed. Another chemical use is in the manufacture of acetyl peroxide. Acetic Anhydride is also used as an intermediate in the manufacture of explosives, weed killers and in the chemical treatment of papers and textiles

Information provided by Celanese Corporation.

Key Words: Acetic Acid Anhydride, Ethanoic Anhydride
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Physical PropertiesMetricEnglishComments
Density 0.00427 g/cc0.000154 lb/in³Vapor density
 1.0442 g/cc
@Temperature 50.0 °C
0.037724 lb/in³
@Temperature 122 °F
 1.0505 g/cc
@Temperature 45.0 °C
0.037952 lb/in³
@Temperature 113 °F
 1.0567 g/cc
@Temperature 40.0 °C
0.038176 lb/in³
@Temperature 104 °F
 1.0628 g/cc
@Temperature 35.0 °C
0.038396 lb/in³
@Temperature 95.0 °F
 1.069 g/cc
@Temperature 30.0 °C
0.03862 lb/in³
@Temperature 86.0 °F
 1.0751 g/cc
@Temperature 25.0 °C
0.038840 lb/in³
@Temperature 77.0 °F
 1.0811 g/cc
@Temperature 20.0 °C
0.039057 lb/in³
@Temperature 68.0 °F
 1.0872 g/cc
@Temperature 15.0 °C
0.039278 lb/in³
@Temperature 59.0 °F
 1.0932 g/cc
@Temperature 10.0 °C
0.039494 lb/in³
@Temperature 50.0 °F
 1.0991 g/cc
@Temperature 5.00 °C
0.039708 lb/in³
@Temperature 41.0 °F
 1.1051 g/cc
@Temperature 0.000 °C
0.039924 lb/in³
@Temperature 32.0 °F
Viscosity  0.62 cP
@Temperature 50.0 °C
0.62 cP
@Temperature 122 °F
 0.65 cP
@Temperature 45.0 °C
0.65 cP
@Temperature 113 °F
 0.70 cP
@Temperature 40.0 °C
0.70 cP
@Temperature 104 °F
 0.74 cP
@Temperature 35.0 °C
0.74 cP
@Temperature 95.0 °F
 0.79 cP
@Temperature 30.0 °C
0.79 cP
@Temperature 86.0 °F
 0.85 cP
@Temperature 25.0 °C
0.85 cP
@Temperature 77.0 °F
 0.91 cP
@Temperature 20.0 °C
0.91 cP
@Temperature 68.0 °F
 0.97 cP
@Temperature 15.0 °C
0.97 cP
@Temperature 59.0 °F
 1.05 cP
@Temperature 10.0 °C
1.05 cP
@Temperature 50.0 °F
 1.13 cP
@Temperature 5.00 °C
1.13 cP
@Temperature 41.0 °F
 1.23 cP
@Temperature 0.000 °C
1.23 cP
@Temperature 32.0 °F
Molecular Weight 102.09 g/mol102.09 g/mol
Vapor Pressure  0.000981 bar
@Temperature 0.000 °C
0.736 torr
@Temperature 32.0 °F
 0.00196 bar
@Temperature 5.00 °C
1.47 torr
@Temperature 41.0 °F
 0.00196 bar
@Temperature 10.0 °C
1.47 torr
@Temperature 50.0 °F
 0.00294 bar
@Temperature 15.0 °C
2.21 torr
@Temperature 59.0 °F
 0.00490 bar
@Temperature 20.0 °C
3.68 torr
@Temperature 68.0 °F
 0.00686 bar
@Temperature 25.0 °C
5.15 torr
@Temperature 77.0 °F
 0.00883 bar
@Temperature 30.0 °C
6.62 torr
@Temperature 86.0 °F
 0.0127 bar
@Temperature 35.0 °C
9.53 torr
@Temperature 95.0 °F
 0.0167 bar
@Temperature 40.0 °C
12.5 torr
@Temperature 104 °F
 0.0216 bar
@Temperature 45.0 °C
16.2 torr
@Temperature 113 °F
 0.0284 bar
@Temperature 50.0 °C
21.3 torr
@Temperature 122 °F
Surface Tension  28.3 dynes/cm
@Temperature 50.0 °C
28.3 dynes/cm
@Temperature 122 °F
 31.2 dynes/cm
@Temperature 30.0 °C
31.2 dynes/cm
@Temperature 86.0 °F
 32.7 dynes/cm
@Temperature 20.0 °C
32.7 dynes/cm
@Temperature 68.0 °F
 
Chemical PropertiesMetricEnglishComments
Critical Pressure 39.9 bar29900 torr
Critical Temperature 332.8 °C631.0 °F
 
Electrical PropertiesMetricEnglishComments
Dielectric Constant 20.5
@Temperature 20.0 °C
20.5
@Temperature 68.0 °F
 
Thermal PropertiesMetricEnglishComments
Heat of Vaporization  460 J/g
@Temperature 50.0 °C
198 BTU/lb
@Temperature 122 °F
 473 J/g
@Temperature 30.0 °C
203 BTU/lb
@Temperature 86.0 °F
 479 J/g
@Temperature 20.0 °C
206 BTU/lb
@Temperature 68.0 °F
CTE, linear 1020 µm/m-°C567 µin/in-°F
Specific Heat Capacity  1.82 J/g-°C
@Temperature 20.0 °C
0.435 BTU/lb-°F
@Temperature 68.0 °F
Liquid
 1.87 J/g-°C
@Temperature 30.0 °C
0.447 BTU/lb-°F
@Temperature 86.0 °F
Liquid
 1.97 J/g-°C
@Temperature 50.0 °C
0.471 BTU/lb-°F
@Temperature 122 °F
Liquid
Thermal Conductivity  0.158 W/m-K
@Temperature 50.0 °C
1.10 BTU-in/hr-ft²-°F
@Temperature 122 °F
 0.163 W/m-K
@Temperature 30.0 °C
1.13 BTU-in/hr-ft²-°F
@Temperature 86.0 °F
 0.165 W/m-K
@Temperature 20.0 °C
1.15 BTU-in/hr-ft²-°F
@Temperature 68.0 °F
Melting Point >= -83.55 °C>= -118.4 °F
Boiling Point 139.5 °C
@Pressure 0.101 MPa
283.1 °F
@Pressure 14.7 psi
Flash Point 49.0 °C120 °F
 
Descriptive Properties
Evaporation Rate0.46(n-Butyl Acetate =1)

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