Applications: Introduced as an easier to handle Pd/P(t-Bu)3-based catalyst for the Negishi cross-coupling of aryl/vinyl chlorides. A versatile catalyst for the cross-coupling of aryl and vinyl chlorides. Catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases. Useful catalyst for the cross-coupling of heteroaromatic carboxylic acids. Pd-catalyzed Newnan-Kwart rearrangement of O-aryl thiocarbamates. Cross-coupling of silanolates and halides. Elimination/isomerization of enol triflates derived from β-ketoesters. Synonyms: Bis(tri-tert - butylphosphine) palladium(0); AK109373; AC-953; tritert-butylphosphane; pd(p(tbu)3)2; AKOS015903145; KS-00000WXP; Bis(tri-t-butylphosphine)palladium (0); FT-0650424; PD(T-BU3P)2 Smiles: CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Pd]; Information provided by Alfa Chemistry Materials. |
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